盛凯
教育及工作经历：
2010年9月-2013年9月 同济大学 工学博士
2014年9月-2015年6月 山东交通学院 讲师
2017年5月-2018年5月 多伦多大学访问学者
2015年7月-至今 山东交通学院 副教授/硕士生导师
研究方向：
金属簇合物；
金属有机框架材料；
稀土发光材料；
配位化学及晶体工程。
科研项目：
1. 2025.01-2027.12，山东省自然科学基金面上项目：铜纳米簇的构筑及性能研究，主持
2. 2021.01-2023.12，山东省自然科学基金面上项目：硅氧烷基稀土纳米团簇的构造、组装机制及性能研究，主持
3. 2014.12-2016.12，山东省优秀中青年科学家科研奖励基金：聚合物基多核稀土复合功能材料的颜色调控和白光发射性能研究，主持
4. 2019.05-2021.05，国家重点实验室开放基金：币基金属掺杂Ti-O纳米团簇光降解印染废水污染物的研究，主持
5.2014.12-2016.12，山东交通学院科研启动基金：新型白光复合材料的制备和荧光性能研究，主持
近年代表性论文：
1.K. Sheng,#Z. Wang,#L. Li, Z.-Y. Gao, C.-H. Tung, D. Sun,* Solvent-Mediated Separation and Reversible Transformation of 1D Supramolecular Polymorphs Built from [W10O32]4–Templated 48-Nuclei Silver(I) Cluster,J. Am. Chem. Soc.,2023,145, 10595-10603.
2.Kai Sheng, Bao-Liang Han, Zhi Wang,* Zhi-Yong Gao, Chen-Ho Tung, Di Sun,*Epitaxial Growth of Silver Clusters from Ag57 to Ag72 via Laminating Multiple Different Anion Templates,Angew. Chem. Int. Ed.,202464,e202416065.
3. W.-D. Si,#K. Sheng,#C. Zhang, Z. Wang, S.-S. Zhang, J.-M. Dou, L. Feng, Z.-Y. Gao, C.-H. Tung, Di Sun,* Bicarbonate insertion triggered self-assembly of chiral octa-gold nanoclusters into helical superstructures in the crystalline state,Chem. Sci.,2022,13, 10523-10531.
4. Q. Liang,#K. Sheng,#A. Salmon, V. Zhou, D. Song*, Active Iron(II) Catalysts Toward Gem-Specific Dimerization of Terminal Alkynes,ACS Catal.,2019,9, 810-818.
5. R. Wang,K. Sheng,* X. Huang,* M. Azam, C.-H. Tung, D. Sun,* A Robust Ag/Ti Nanocluster as an Efficient Heterogeneous Lewis Acid-Base Catalyst for C-C Bond Formation,J. Catal.,2023,424, 189-196.
6.K.Sheng, Y.-N. Liu, R. K. Gupta,* M. Kurmoo, D. Sun,*Arylazopyrazole-Functionalized Photoswitchable Octanuclear Zn(II)-Silsesquioxane Nanocage,Sci. China Chem.,2021,64, 419-425.
7.K. Sheng,#L. M. Fan,#X. Tian, R. K. Gupta,* L. Gao, C. H. Tung, D. Sun*, Temperature-Induced Sn(II) Supramolecular Isomeric Frameworks as Promising Heterogeneous Catalysts for Cyanosilylation of Aldehydes,Sci. China Chem.,2020,63, 182-186.
8.K. Sheng, X. F. Tian, M. Jagodič,* Z. Jagličić, N. Zhang,* Q. Liu, C. H. Tung, D. Sun,* Synthesis,Structure and Magnetism of a Novel CuII4TiIV5Heterometallic Cluster,Chin. Chem. Lett.,2020,31, 809-812.
9.K. Sheng, H. F. Lu,* A. Sun, Y. M. Wang,* Y. T. Liu, F. Chen, W. C. Bian, Y. Li, R. Kuang, D. Sun,* A Naked-Eye Colorimetric Sensor for Chloroform,Chin. Chem. Lett.,2019,30, 895-898.
10.K. Sheng,#X.-Q. Huang,#R. Wang, W.-Z. Wang, Z.-Y. Gao, C.-H. Tung, Di Sun,* Decagram-scale synthesis of heterometallic Ag/Ti cluster as sustainable catalyst for selective oxidation of sulfides,J. Catal.,2023,417, 185-193.
11.Q.Shen,K.Sheng,*Z.-Y.Gao,A.Bilyachenko,X.-Q.Huang,*M.Azam,C.-H.Tung,D.Sun,*Vanadium-Silsesquioxane Nanocages as Heterogeneous Catalysts for Synthesis of Quinazolinones,Inorg. Chem.,2024,63, 13022-13030.
12.K. Sheng,#W. D. Si,#R. Wang, W. Z. Wang, J, Dou, Z. Y. Gao, L. K. Wang, C. H. Tung, D. Sun,* Keggin-Type Tridecanuclear Europium-Oxo Nanocluster Protected by Silsesquioxanes,Chem. Mater.,2022,34, 4186-4194.
13.K. Sheng, R. Wang, X. Tang, M. Jagodič,* Z. Jagličić, L. Pang, J.-M. Dou, Z.-Y. Gao, H.-Y. Feng,* C.-H. Tung, Di Sun,* A Carbonate-Templated Decanuclear Mn Nanocage with Two Different Silsesquioxane Ligands,Inorg. Chem.,2021,60, 14866-14871.
14. Y.Yuan,#K. Sheng,#G. Zhuang,#Q. Li,#C. Dou, Q.-J. Fang, W.-W. Zhan,* H. Gao, D. Sun,* X. Han,* Collaboratively Boosting Charge Transfer and CO2Chemisorption of SnO2to Selectively Reduce CO2to HCOOH,Chem. Commun.,2021,57, 8636-8639.
15.Y. S. Yuan,#K. Sheng,#S. Y. Zeng, X. G. Han,* L. M. Sun, I. Lončarić,* W. W. Zhan, D. Sun,* Engineering Cu/TiO2@N-Doped C Interfaces Derived from an Atom Precise Heterometallic CuII4TiIV5Cluster for Efficient Photocatalytic Hydrogen Evolution,Inorg. Chem.,2020,59, 5456-5462.
16. X.-F. Tian, B.-Q. Ji, L. Feng,K. Sheng,* Y.-M. Su, M. Jagodič,* Z. Jagličić, C.-H. Tung, D. Sun,* Self-Assembly of a Nonanuclear NiIIClusterviaAtmospheric CO2Fixation: Synthesis, Structure, Collision-Induced Dissociation Mass Spectrometry and Magnetic Property,Dalton Trans.,2020,49, 10977-10982.
